USA The Hitt Companies, Inc. www.HittMarking.com USA
Page 1/7
Material Safety Data Sheet
acc. to ISO/DIS 11014
09/23/2009 Revision date: 07/21/2009
1 Identification of substance:
Product details:
Trade name: R-1 and R-22 Ink
Application of the substance / the preparation Printing inks
Manufacturer/Supplier:
Diagraph MSP, The Hitt Companies, Inc.
www.HittMarking.com
National Stencil Marking & Stenciling Products Division
www.NationalStencil.com
The Hitt Companies, Inc. National Stencil Marking & Stenciling Products Division
3231 W. MacArhur Blvd.
Santa Ana, CA 92704
USA
Customer Sales & Service:
714-979-1405
714-979-140 Fax
Information Department: Sales@HittCompanies.com@HittCompanies.com
Emergency information:
Contact Infotrac: (800) 969-6699 (US only)
International: +1 714 979 1405
2 Composition/Data on components:
Chemical characterization
Description: Mixture of the substances listed below with nonhazardous additions.
Dangerous components:
123-42-2 4-hydroxy-4-methylpentan-2-one 80-100%
123-42-2 4-hydroxy-4-methylpentan-2-one 80-100%
111-46-6 Diethylene glycol 0-5%
Additional information For the wording of the listed risk phrases refer to section 16.
3 Hazards identification
Hazard description:
Irritant
Irritant
Information pertaining to particular dangers for man and environment:
The product has to be labelled due to the calculation procedure of the "General Classification
The product has to be labelled due to the calculation procedure of the "General Classification
guideline for preparations of the EU" in the latest valid version.
Irritating to eyes.
To avoid risks for humans and environment obtain instructions.
Classification system
The classification was made according to the latest editions of international substances lists, and
The classification was made according to the latest editions of international substances lists, and
expanded upon from company and literature data.
NFPA Ratings (scale 0-4)
Printing inks Diagraph MSP, an ITW Company, Mixture of the substances listed below with nonhazardous additions. 123-42-2 4-hydroxy-4-methylpentan-2-one 80-100%For the wording of the listed risk phrases refer to section 16. IrritantThe product has to be labelled due to the calculation procedure of the "General ClassificationThe classification was made according to the latest editions of international substances lists, and
Printing inks Diagraph MSP, an ITW Company, Mixture of the substances listed below with nonhazardous additions. 123-42-2 4-hydroxy-4-methylpentan-2-one 80-100%For the wording of the listed risk phrases refer to section 16. IrritantThe product has to be labelled due to the calculation procedure of the "General ClassificationThe classification was made according to the latest editions of international substances lists, and
Printing inks msds@diagraphmsp.com Mixture of the substances listed below with nonhazardous additions. For the wording of the listed risk phrases refer to section 16.
Printing inks msds@diagraphmsp.com Mixture of the substances listed below with nonhazardous additions. For the wording of the listed risk phrases refer to section 16.
0
Health = 2
Fire = 2
Reactivity = 0
HMIS Rating (scale 0-4)
REACTIVITY
2
2
0
Health - 2
Flammability - 2
Reactivity - 0
Routes of Entry
Ingestion
Ingestion
Inhalation
(Contd. on page 2)
USA
Page 2/7
Material Safety Data Sheet
acc. to ISO/DIS 11014
09/23/2009 Revision date: 07/21/2009
Trade name:
R-1 and R-22 Ink (Contd. of page 1) Target Organs Eyes
Irritancy
Eyes
Eyes
Respiratory Tract
Skin
Sensitizing Capability None known
Reproductive Effects None known Cancer Information Not known to be carcinogenic.
4 First aid measures
After inhalation Supply fresh air; consult doctor in case of complaints.
After skin contact Generally the product does not irritate the skin.
After eye contact
Rinse opened eye for several minutes under running water. If symptoms persist, consult a doctor.
Rinse opened eye for several minutes under running water. If symptoms persist, consult a doctor.
Rinse opened eye for several minutes under running water. Then consult a doctor.
After swallowing
If swallowed, do not induce vomiting: seek medical advice immediately and show this container or
If swallowed, do not induce vomiting: seek medical advice immediately and show this container or
label
5 Fire fighting measures
Suitable extinguishing agents
CO2, extinguishing powder or water spray. Fight larger fires with water spray or alcohol resistant
CO2, extinguishing powder or water spray. Fight larger fires with water spray or alcohol resistant
foam.
Protective equipment: No special measures required.
6 Accidental release measures
Person-related safety precautions: Not required.
Measures for environmental protection:
Inform respective authorities in case of seepage into water course or sewage system.
Inform respective authorities in case of seepage into water course or sewage system.
Measures for cleaning/collecting:
Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust).
Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust).
Ensure adequate ventilation.
7 Handling and storage
Handling
Information for safe handling:
Ensure good ventilation/exhaustion at the workplace.
Ensure good ventilation/exhaustion at the workplace.
Prevent formation of aerosols.
Wash hands thoroughly after handling.
Information about protection against explosions and fires: No special measures required.
Storage
Requirements to be met by storerooms and receptacles: No special requirements.
Information about storage in one common storage facility: Not required.
Further information about storage conditions: Keep receptacle tightly sealed.
Maximum storage temperature: 120 F (49 C)
Minimum storage temperature 35 F (2 C)
Eyes None known None known Not known to be carcinogenic. Supply fresh air; consult doctor in case of complaints. Generally the product does not irritate the skin. No special measures required. Not required. No special measures required. No special requirements. Not required. Keep receptacle tightly sealed. 120 F (49 C) 35 F (2 C)
USA
(Contd. on page 3)
Page 3/7
Material Safety Data Sheet
acc. to ISO/DIS 11014
09/23/2009 Revision date: 07/21/2009
Trade name:
R-1 and R-22 Ink
(Contd. of page 2)
DR
8 Exposure controls and personal protection
Additional information about design of technical systems: No further data; see item 7.
Components with limit values that require monitoring at the workplace:
123-42-2 4-hydroxy-4-methylpentan-2-one
PEL
PEL
REL
TLV
240 mg/m³, 50 ppm
240 mg/m³, 50 ppm
238 mg/m³, 50 ppm
111-46-6 Diethylene glycol
WEEL 10 mg/m³
62-53-3 aniline
PEL
REL
TLV
19 mg/m³, 5 ppm
and Homologues; Skin
and Homologues; LFC
7.6 mg/m³, 2 ppm
Skin; BEI
Personal protective equipment
General protective and hygienic measures
Keep away from foodstuffs, beverages and feed.
Keep away from foodstuffs, beverages and feed.
Immediately remove all soiled and contaminated clothing
Wash hands before breaks and at the end of work.
Avoid contact with the eyes.
Avoid contact with the eyes and skin.
Breathing equipment:
In case of brief exposure or low pollution use respiratory filter device. In case of intensive or longer
In case of brief exposure or low pollution use respiratory filter device. In case of intensive or longer
exposure use respiratory protective device that is independent of circulating air.
Protection of hands:
Protective gloves.
Protective gloves.
The glove material has to be impermeable and resistant to the product/ the substance/ the preparation.
Selection of the glove material on consideration of the penetration times, rates of diffusion and the
degradation
Material of gloves
Butyl rubber, BR
Butyl rubber, BR
Nitrile rubber, NBR
Natural rubber, NR
PVA gloves
Neoprene gloves
The selection of the suitable gloves does not only depend on the material, but also on further marks of
quality and varies from manufacturer to manufacturer. As the product is a preparation of several
substances, the resistance of the glove material can not be calculated in advance and has therefore to
be checked prior to the application.
Penetration time of glove material
The exact break through time has to be found out by the manufacturer of the protective gloves and has
The exact break through time has to be found out by the manufacturer of the protective gloves and has
to be observed.
Not suitable are gloves made of the following materials:
Leather gloves
Leather gloves
PVC gloves
(Contd. on page 4)
No further data; see item 7.
USA
Page 4/7
Material Safety Data Sheet
acc. to ISO/DIS 11014
09/23/2009 Revision date: 07/21/2009
Trade name:
R-1 and R-22 Ink
(Contd. of page 3)
Eye protection:
Tightly sealed goggles.
Tightly sealed goggles.
9 Physical and chemical properties:
General Information
Form:
Liquid
Color:
According to product specification
According to product specification
Odor:
Characteristic
Change in condition
Melting point/Melting range:
undetermined
Boiling point/Boiling range:
150°C (302°F)
150°C (302°F) Flash point: 56°C (133°F)
Ignition temperature: 620°C (1148°F)
Auto igniting: Product is not selfigniting.
Danger of explosion: Product does not present an explosion hazard.
Explosion limits:
Lower:
1.4 Vol %
Upper:
8.1 Vol %
8.1 Vol % Vapor pressure at 20°C (68°F): 1.1 hPa (1 mm Hg)
Density at 20°C (68°F): 0.96 g/cm³
Solubility in / Miscibility with
Water:
Partly miscible
Partly miscible
Solvent content:
Organic solvents:
94.8 %
Solids content: 5.0 %
10 Stability and reactivity
Thermal decomposition / conditions to be avoided:
No decomposition if used according to specifications.
No decomposition if used according to specifications.Dangerous reactions No dangerous reactions known
Dangerous products of decomposition: No dangerous decomposition products known
11 Toxicological information
Acute toxicity:
Primary irritant effect:
on the skin: No irritant effect.
on the eye: Irritating effect.
Sensitization: No sensitizing effects known.
Additional toxicological information:
The product shows the following dangers according to internally approved calculation methods for
The product shows the following dangers according to internally approved calculation methods for
preparations:
(Contd. on page 5)
Tightly sealed goggles.56°C (133°F) 620°C (1148°F) 1.1 hPa (1 mm Hg) 0.96 g/cm³ Partly miscible No decomposition if used according to specifications.No dangerous reactions known No dangerous decomposition products known No irritant effect. Irritating effect. No sensitizing effects known. The product shows the following dangers according to internally approved calculation methods for
USA
Page 5/7
Material Safety Data Sheet
acc. to ISO/DIS 11014
09/23/2009 Revision date: 07/21/2009
Trade name:
R-1 and R-22 Ink
(Contd. of page 4)
DR
Irritant
13 Disposal considerations
Product:
Recommendation
Must not be disposed of together with household garbage. Do not allow product to reach sewage
Must not be disposed of together with household garbage. Do not allow product to reach sewage
system.
Comply with all Federal, State, and Local regulations regarding disposal.
Uncleaned packagings:
Recommendation:
Disposal must be made according to official regulations.
Disposal must be made according to official regulations.
Comply with all Federal, State, and Local regulations regarding disposal.
14 Transport information
DOT regulations: Non-regulated Material
Hazard class: 3
Identification number: UN1210
Packing group: III
ERG # 129
Proper shipping name (technical name): PRINTING INK
Label 3
Remarks: Note: For domestic GROUND shipments for non-bulk
packaging (119 gallons or less), this material may be
classified as a 'COMBUSTIBLE' under 49 CFR 173.150(f).
Therefore no labels or hazardous materials shipping papers
are required for domestic ground shipments for non-bulk
packaging of this product.
Land transport ADR/RID (cross-border)
ADR/RID class: 3 Flammable liquids
3 Flammable liquids
Danger code (Kemler): 30
UN-Number: 1210
Packaging group: III
Description of goods: 1210 PRINTING INK (not viscous)
1210 Printing ink
Maritime transport IMDG:
MDG Class: 3
3
UN Number: 1210
Label 3
Packaging group: III
EMS Number: F-E,S-D
Marine pollutant: No
(Contd. on page 6)
USA
Page 6/7
Material Safety Data Sheet
acc. to ISO/DIS 11014
09/23/2009 Revision date: 07/21/2009
Trade name:
R-1 and R-22 Ink (Contd. of page 5)
Propper shipping name: PRINTING INK
Air transport ICAO-TI and IATA-DGR:
ICAO/IATA Class: 3
3
UN/ID Number: 1210
Label 3
Packaging group: III
Propper shipping name: PRINTING INK
15 Regulations
ancerogenity categories
EPA (Environmental Protection Agency)
62-53-3 aniline B2
62-53-3 aniline B2
IARC (International Agency for Research on Cancer)
62-53-3 aniline 3
62-53-3 aniline 3
NTP (National Toxicology Program)
None of the ingredients is listed.
None of the ingredients is listed.
TLV (Threshold Limit Value established by ACGIH)
62-53-3 aniline A3
62-53-3 aniline A3
MAK (German Maximum Workplace Concentration)
62-53-3 aniline 4
62-53-3 aniline 4
NIOSH-Ca (National Institute for Occupational Safety and Health)
62-53-3 aniline
62-53-3 aniline
OSHA-Ca (Occupational Safety & Health Administration)
62-53-3 aniline
62-53-3 aniline
Product related hazard information:
The product has been classified and marked in accordance with directives on hazardous materials.
The product has been classified and marked in accordance with directives on hazardous materials.
Hazard symbols:
Irritant
Irritant
Risk phrases:
Irritating to eyes.
Irritating to eyes.
Safety phrases:
Keep out of the reach of children.
Keep out of the reach of children.
Do not breathe gas/fumes/vapour/spray.
Avoid contact with skin and eyes.
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
Do not empty into drains, dispose of this material and its container at hazardous or special waste
collection point
If swallowed, seek medical advice immediately and show this container or label.
Special labeling of certain preparations:
To avoid risks for humans and environment obtain instructions.
To avoid risks for humans and environment obtain instructions.
(Contd. on page 7)
3 62-53-3 aniline B262-53-3 aniline 3None of the ingredients is listed. 62-53-3 aniline A362-53-3 aniline 462-53-3 anilineIrritant
USA
Page 7/7
Material Safety Data Sheet
acc. to ISO/DIS 11014
09/23/2009 Revision date: 07/21/2009
Trade name:
R-1 and R-22 Ink
(Contd. of page 6)
(Contd. of page 6)
National regulations
Other regulations, limitations and prohibitive regulations
OSHA Regulations
Air Contaminant (29 CFR 1910.1000, Table Z-1, Z-1-A): Not listed
Air Contaminant (29 CFR 1910.1000, Table Z-1, Z-1-A): Not listed
OSHA Specifically Regulated Substance (29 CFR 1910.): Not listed
Superfund Amendments and Reauthorization Act of 1986 (SARA) Title III, Section 313:
This product does not contain chemicals listed as toxic chemicals at levels which require reporting
This product does not contain chemicals listed as toxic chemicals at levels which require reporting
under SARA Title III Section 313.
CONEG:
This product meets CONEG and RoHS legislation for low levels of Lead, Cadmium, Mercury,
This product meets CONEG and RoHS legislation for low levels of Lead, Cadmium, Mercury,
Hexavalent Chrome, and Brominated flame retardants.
Lead (Pb) < 10 ppm
Mercury (Hg) < 5 ppm
Hexavalent Chrome (CR+6) < 7 ppm
Total Bromine (Br) 52 ppm
Cadmium (Cd) < 7 ppm
Toxic Substances Control Act TSCA Status:
All components of this product are listed in the EPA's Inventory of Chemical Substances as required
All components of this product are listed in the EPA's Inventory of Chemical Substances as required
under the Toxic Substances Control Act (TSCA).
California Proposition 65 (Chemicals known to cause cancer):
62-53-3 aniline
62-53-3 aniline
California Proposition 65 (Chemicals known to cause reproductive toxicity):
This product contains no ingredients on the California Proposition 65 known to cause reproductive
This product contains no ingredients on the California Proposition 65 known to cause reproductive
toxicity.
16 Other information:
This information is based on our present knowledge. However, this shall not constitute a guarantee for
any specific product features and shall not establish a legally valid contractual relationship.
Department issuing MSDS: Chemistry
MSDS Created By: Peter Gimse
File: 124
Revision Information (All previous revisions obsolete):
This Revision: 7/25/2008 Section 1: Added R-22 and Removed Product Numbers; Section 2: Updated
Health Rating, Section 9: Changed Color to reflect addition of red; Section 15: Updated CONEG,
RoHs, and Prop 65
Previous Revisions:
1/1/2005 Removed Hexylene Glycol
2/26/2002 Updated Company Info
8/11/2000 Section 1: updated product numbers. Section 14: Added ERG#. Corrected IMDG page
number
09/20/1999 Initial Release
Air Contaminant (29 CFR 1910.1000, Table Z-1, Z-1-A): Not listedThis product does not contain chemicals listed as toxic chemicals at levels which require reportingThis product meets CONEG and RoHS legislation for low levels of Lead, Cadmium, Mercury,All components of this product are listed in the EPA's Inventory of Chemical Substances as required62-53-3 anilineThis product contains no ingredients on the California Proposition 65 known to cause reproductive
USA The Hitt Companies, Inc. www.HittMarking.com USA